Microreactors in Organic Chemistry and Catalysis - 16 Angebote vergleichen

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Microreactors in Organic Chemistry and Catalysis: InhaltsangabePreface to the First Edition XIIIPreface to the Second Edition XVList of Contributors XVII1 Properties and Use of Microreactors 1 David Barrow, Shan Taylor, Alex Morgan, and Lily Giles1.1 Introduction 11.1.1 A Brief History of Microreactors 11.1.2 Advantages of Microreactors 61.2 Physical Characteristics of Microreactors 71.2.1 Geometries 71.2.2 Constructional Materials and Their Properties 101.3 Fluid Flow and Delivery Regimes 161.3.1 Fluid Flow 161.3.2 Fluid Delivery 201.3.3 Mixing Mechanisms 211.4 Multifunctional Integration 231.5 Uses of Microreactors 231.5.1 Overview 231.5.1.1 Fast and Exothermic Reactions 241.5.2 Precision Particle Manufacture 251.5.3 Wider Industrial Context 271.5.3.1 Sustainability Agenda 271.5.3.2 Point-of-Demand Synthesis 27References 282 Fabrication of Microreactors Made from Metals and Ceramic 35 Juergen J. Brandner2.1 Manufacturing Techniques for Metals 352.2 Etching 362.3 Machining 382.4 Generative Method: Selective Laser Melting 412.5 Metal Forming Techniques 422.6 Assembling and Bonding of Metal Microstructures 432.7 Ceramic Devices 462.8 Joining and Sealing 48References 493 Microreactors Made of Glass and Silicon 53 Thomas Frank3.1 How Microreactors Are Constructed 533.1.1 Glass As Material 543.1.2 Silicon As Material 573.2 The Structuring of Glass and Silicon 583.2.1 Structuring by Means of Masked Etching As in Microsystems Technology 583.2.2 Etching Technologies 603.2.2.1 Anisotropic (Crystallographic) Wet Chemical Etching of Silicon (KOH) 613.3 Isotropic Wet Chemical Etching of Silicon 633.3.1.1 Isotropic Wet Chemical Etching of Silicon 643.3.1.2 Isotropic Wet Chemical Etching of Silicon Glass 653.3.2 Other Processes 663.3.2.1 Photostructuring of Special Glass 663.3.3 Drilling, Diamond Lapping, Ultrasonic Lapping 683.3.4 Micro Powder Blasting 693.3.5 Summary 713.4 Other Processes 723.4.1 Sensor Integration 723.5 Thin Films 723.6 Bonding Methods 733.6.1 Anodic Bonding of Glass and Silicon 733.6.2 Glass Fusion Bonding 733.6.3 Silicon Direct Bonding (Silicon Fusion Bonding) 743.6.4 Establishing Fluid Contact 763.7 Other Materials 78References 794 Automation in Microreactor Systems 81 Jason S. Moore and Klavs F. Jensen4.1 Introduction 814.2 Automation System 844.3 Automated Optimization with HPLC Sampling 864.4 Automated Multi-Trajectory Optimization 894.5 Kinetic Model Discrimination and Parameter Fitting 944.6 Conclusions and Outlook 97References 995 Homogeneous Reactions 101 Takahide Fukuyama, Md. Taifur Rahman, and Ilhyong Ryu5.1 Acid-Promoted in Flow Synthesis 1527.2 Immobilization of the Reagent/Catalyst 1557.2.1 A Packed-Bed Reactor 1557.2.2 Monolith Reactors 1567.2.3 Miscellaneous 1577.3 Flow Reactions with an Immobilized Stoichiometric Reagent 1597.4 Flow Synthesis with Immobilized Catalysts: Solid Acid Catalysts 1657.5 Flow Reaction with an Immobilized Catalyst: Transition Metal Catalysts Dispersed on Polymer 1667.5.1 Catalytic Hydrogenation 1677.5.2 Catalytic Cross-Coupling Reactions and Carbonylation Reactions 1717.5.3 Miscellaneous 1757.6 Flow Reaction with an Immobilized Catalyst: Metal Catalysts Coordinated by a Polymer-Supported Ligand 1767.6.1 Flow Reactions Using Immobilized Ligands with a Transition Metal Catalyst 1797.7 Organocatalysis in Flow Reactions 1837.8 Flow Biotransformation Reactions Catalyzed by Immobilized Enzymes 1867.9 Multistep Synthesis 1877.10 Conclusion 191References 1918 Liquid&ndash Liquid Biphasic Reactions 197 Matthew J. Hutchings, Batool Ahmed-Omer, and Thomas Wirth8.1 Introduction 1978.2 Background 1988.3 Kinetics of Biphasic Systems 1998.4 Biphasic Flow in Microchannels 2008.5 Surface and Liquid&ndash Liquid Interaction 2028.6 Liquid&ndash Liquid Microsystems in Organic Synthesis 2078.7 Micromixer 2098.8 Conclusions and Outlook 218References 2189 Gas&ndash Liquid Reactions 221 Ivana Dencic and Volker Hessel9.1 Introduction 2219.2 Contacting Principles and Microreactors 2229.2.1 Contacting with Continuous Phases 2229.2.1.1 Falling Film Microreactor 2229.2.1.2 Continuous Contactor with Partly Overlapping Channels 2269.2.1.3 Mesh Microcontactor 2279.2.1.4 Annular-Flow Microreactors 2299.2.2 Contacting with Disperse Phases 2319.2.2.1 Taylor-Flow Microreactors 2329.2.2.2 Micromixer-Capillary/Tube Reactors 2379.2.2.3 Micro-packed Bed Reactors 2409.2.2.4 Membrane Microreactors 2429.2.2.5 Tube in Tube Microreactor 2439.2.3 Scaling Up of Microreactor Devices 2449.3 Gas&ndash Liquid Reactions 2459.3.1 Direct Fluorination of Aromatics 2469.3.1.1 Direct Fluorination of Aromatics 2469.3.1.2 Direct Fluorination of Aliphatics and Non-C-Moieties 2499.3.1.3 Direct Fluorination of Heterocyclic Aromatics 2519.3.2 Oxidations of Alcohols, Diols, and Ketones with Fluorine 2539.3.3 Photochlorination of Aromatic Isocyanates 2549.3.4 Photoradical Chlorination of Cycloalkenes 2559.3.5 Mono-Chlorination of Acetic Acid 2569.3.6 Sulfonation of Toluene 2579.3.7 Photooxidation Reactions 2599.3.8 Reactive Carbon Dioxide Absorption 2639.4 Gas&ndash Liquid&ndash Solid Reactions 2659.4.1 Hydrogenations 2669.4.1.1 Cyclohexene Hydrogenation over Pt/Al2O3 2669.4.1.2 Hydrogenation of p-Nitrotoluene and Nitrobenzene over Pd/C and Pd/Al2O3 2679.4.1.3 Hydrogenation of Azide 2709.4.1.4 Hydrogenation of Pharmaceutical Intermediates 2709.4.1.5 Selective Hydrogenation of Acetylene Alcohols 271< Oligosaccharide, and Oligonucleotide 29210.2.1.1 Peptide Synthesis 29210.2.1.2 Sugar and Oligosaccharide Synthesis 29610.2.1.3 Oligonucleotide Synthesis 30210.3 Biocatalysis by Enzymatic Microreactors 30410.3.1 Classification of Enzymatic Microreactors Based on Application 30410.3.1.1 Applications of Microreactors for Enzymatic Diagnostics and Genetic Analysis 30410.3.1.2 Application of Microreactors for Enzyme-Linked Immunoassays 30810.3.1.3 Applications of Microfluidic Enzymatic Microreactors in Proteomics 31210.3.2 Enzymatic Microreactors for Biocatalysis 34710.3.3 Advantages of Microreactors in Biocatalysis 34710.3.4 Biocatalytic Transformations in Microfluidic Systems 34810.3.4.1 Solution-phase Enzymatic Reactions 34810.3.4.2 Microfluidic Reactors with Immobilized Enzymes for Biocatalytic Transformations 35710.4 Multienzyme Catalysis in Microreactors 36210.5 Conclusions 365References 36611 Industrial Microreactor Process Development up to Production 373 Ivana Dencic and Volker Hessel11.1 Mission Statement from Industry on Impact and Hurdles 37311.2 Screening Studies in Laboratory 37511.2.1 Peptide Synthesis 37511.2.2 Hantzsch Synthesis 37811.2.3 Knorr Synthesis 37911.2.4 Enamine Synthesis 38111.2.5 Aldol Reaction 38111.2.6 Wittig Reaction 38211.2.7 Polyethylene Formation 38211.2.8 Diastereoselective Alkylation 38311.2.9 Multistep Synthesis of a Radiolabeled Imaging Probe 38411.3 Process Development at Laboratory Scale 38611.3.1 Nitration of Substituted Benzene Derivatives 38611.3.2 Microflow Azide Syntheses 38711.3.3 Vitamin Precursor Synthesis 38911, Englisch, Ebook.

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For the second edition of ´Microreactors in Organic Chemistry and Catalysis´ all chapters have been revised and updated to reflect the latest developments in this rapidly developing field. This new edition has 60% more content, and it remains a comprehensive publication covering most aspects of the topic. The use of microreactors in homogeneous, heterogeneous as well as biphasic reactions is covered in the main part of the book, together with catalytic, bioorganic and automation approaches. The initial chapters also provide a solid physical chemistry background on fluidics in microdevices. Finally, a chapter on industrial applications and developments covers recent progress in process chemistry. An excellent reference for beginners and experts alike. 27.02.2013, PDF.

For the second edition of ´Microreactors in Organic Chemistry and Catalysis´ all chapters have been revised and updated to reflect the latest developments in this rapidly developing field. This new edition has 60% more content, and it remains a comprehensive publication covering most aspects of the topic. The use of microreactors in homogeneous, heterogeneous as well as biphasic reactions is covered in the main part of the book, together with catalytic, bioorganic and automation approaches. The initial chapters also provide a solid physical chemistry background on fluidics in microdevices. Finally, a chapter on industrial applications and developments covers recent progress in process chemistry. An excellent reference for beginners and experts alike. 22.02.2013, ePUB.

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Microreactors in Organic Chemistry and Catalysis, For the second edition of ´Microreactors in Organic Chemistry and Catalysis´ all chapters have been revised and updated to reflect the latest developments in this rapidly developing field. This new edition has 60% more content, and it remains a comprehensive publication covering most aspects of the topic. The use of microreactors in homogeneous, heterogeneous as well as biphasic reactions is covered in the main part of the book, together with catalytic, bioorganic and automation approaches. The initial chapters also provide a solid physical chemistry background on fluidics in microdevices. Finally, a chapter on industrial applications and developments covers recent progress in process chemistry. An excellent reference for beginners and experts alike. PDF, 27.02.2013.

Lieferung aus: Schweiz, Sofort per Download lieferbar.
Microreactors in Organic Chemistry and Catalysis, For the second edition of ´Microreactors in Organic Chemistry and Catalysis´ all chapters have been revised and updated to reflect the latest developments in this rapidly developing field. This new edition has 60% more content, and it remains a comprehensive publication covering most aspects of the topic. The use of microreactors in homogeneous, heterogeneous as well as biphasic reactions is covered in the main part of the book, together with catalytic, bioorganic and automation approaches. The initial chapters also provide a solid physical chemistry background on fluidics in microdevices. Finally, a chapter on industrial applications and developments covers recent progress in process chemistry. An excellent reference for beginners and experts alike. ePUB, 22.02.2013.

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For the second edition of 'Microreactors in Organic Chemistry and Catalysis' all chapters have been revised and updated to reflect the latest developments in this rapidly developing field. This new edition has 60% more content, and it remains a co.

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For the second edition of 'Microreactors in Organic Chemistry and Catalysis' all chapters have been revised and updated to reflect the latest developments in this rapidly developing field. This new edition has 60% more content, and it remains a comprehensive publication covering most aspects of the topic. The use of microreactors in homogeneous, heterogeneous as well as biphasic reactions is covered in the main part of the book, together with catalytic, bioorganic and automation approaches. The initial chapters also provide a solid physical chemistry background on fluidics in microdevices. Finally, a chapter on industrial applications and developments covers recent progress in process chemistry. An excellent reference for beginners and experts alike.

Lieferung aus: Vereinigtes Königreich Großbritannien und Nordirland, Despatched same working day before 3pm.
For the second edition of 'Microreactors in Organic Chemistry and Catalysis' all chapters have been revised and updated to reflect the latest developments in this rapidly developing field. This new edition has 60% more content, and it remains a comprehensive publication covering most aspects of the topic. The use of microreactors in homogeneous, heterogeneous as well as biphasic reactions is covered in the main part of the book, together with catalytic, bioorganic and automation approaches. The initial chapters also provide a solid physical chemistry background on fluidics in microdevices. Finally, a chapter on industrial applications and developments covers recent progress in process chemistry. An excellent reference for beginners and experts alike.

Lieferung aus: Vereinigtes Königreich Großbritannien und Nordirland, Despatched same working day before 3pm.
For the second edition of 'Microreactors in Organic Chemistry and Catalysis' all chapters have been revised and updated to reflect the latest developments in this rapidly developing field. This new edition has 60% more content, and it remains a comprehensive publication covering most aspects of the topic. The use of microreactors in homogeneous, heterogeneous as well as biphasic reactions is covered in the main part of the book, together with catalytic, bioorganic and automation approaches. The initial chapters also provide a solid physical chemistry background on fluidics in microdevices. Finally, a chapter on industrial applications and developments covers recent progress in process chemistry. An excellent reference for beginners and experts alike.

Lieferung aus: Vereinigtes Königreich Großbritannien und Nordirland, Despatched same working day before 3pm.
For the second edition of 'Microreactors in Organic Chemistry and Catalysis' all chapters have been revised and updated to reflect the latest developments in this rapidly developing field. This new edition has 60% more content, and it remains a comprehensive publication covering most aspects of the topic. The use of microreactors in homogeneous, heterogeneous as well as biphasic reactions is covered in the main part of the book, together with catalytic, bioorganic and automation approaches. The initial chapters also provide a solid physical chemistry background on fluidics in microdevices. Finally, a chapter on industrial applications and developments covers recent progress in process chemistry. An excellent reference for beginners and experts alike.